Cleaning up my closet – home testing silver

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Springtime, time for cleaning up one’s closet. Everybody has somewhere a piece of antique silverware… wow, it rhymes 🙂 But is the precious grandmother’s piece real silver? One can always go to the specialist to have it tested, but as a hobby silver jewelry maker you would really like to do it yourself at home.
I found these two pieces in my closet: a silver-colored brooch hallmarked 835 and a piece of flatware probably used for holding napkins. The latter really intrigued me, because of a possibility to use it in a handmade jewelry piece. So I decided to test it with available home testing methods and the brooch as a reference.

Here is my test protocol for home testing silver

 

Scratching with abrasive tool

 

Step 1 Visual examination

Both of the pieces feel the same (in strength, density, weight) and look the same (same silver shine). Since I know that silver content in flatware can be anything from 750 up to 800 – 820 – 825- 830 – 835 – 850, the tested piece can be anything in this range, containing up to 25% metals other than silver. It can also be silver-plated or nickel silver – an alloy of copper, zinc and nickel.

 

 

 

 

Silver shine when scratched

Step 2. Is the piece solid or coated (silver-plated)? 
The answer can be easily obtained by scratching the surface (in the place where it is least seen). I did it using an abrasive tool – and the result was clear. There was no coating, it was one piece.The shine on the scratched surface was ‘silvery’. On the other hand, the metal felt much harder than sterling silver I normally work with. That was already the first  “sign” that the piece was not silver.

 

 

 

 

 

 

Applying LOS to both pieces

Step 3. Testing.  Among all techniques found on the internet for home testing silver at home I have chosen the two available:
a) Magnet and

b) Liver of Sulfur.

The reason for the choice was that I don’t have nitric acid (and this stuff is very corrosive too) at home. I don’t trust the “ice” method either.

The result was the following. Both pieces did not stick to a piece of magnet. And both pieces reacted with the LOS, by forming a tarnish when heated.

835-Brooch tarnished by LOS

 

 Step 4. Analytic table. What metal could it be, other than silver?

Metal
Magnetic (Y/N)
Tarnished by LOS (Y/N)
Different from silver? (look, shine, touch, smell…)
Nickel
Y
Y or N
shine, hardness
Zinc
N
N
shine, color
Stainless steel
Y or N
N
shine, hardness
Nickel-silver alloy (Ni-Cu-Zn)
N
Y or N
looks very much like silver!
Chromium
N
N
shine, hardness
Aluminum
N
N
much lighter
Tin
Y or N
N
softer, different shine and color
Copper
N
Y
color, smell etc
Brass
N
Y or N
color etc
Bronze
N
Y
color etc
Conclusion: The fact that a piece looks like silver and reacts like silver with magnets and liver of sulfur does not give a 100% guarantee that the piece is made of sterling silver. Nickel silver can also behave in the same way. So I will probably have to order a chemical acid testing kit to be sure that this inherited ‘treasure’  is genuine sterling silver.
Tarnished by LOS, but does it mean it is silver?

P.S. The above piece has been tested with test fluid and the final verdict is: NOT silver.

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